188407-84-3

Basic information

• Product Name: Propanedioic acid, methyl(4-methyl-2-nitrophenoxy)-, monomethyl ester, (2R)-
• CAS NO: 188407-84-3
• Molecular Formula: C12H13NO7
• Molecular Weight: 283.238
• Mol File: 188407-84-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Propanedioic acid, methyl(4-methyl-2-nitrophenoxy)-, monomethyl ester, (2R)-(CAS DataBase Reference)
• NIST Chemistry Reference: Propanedioic acid, methyl(4-methyl-2-nitrophenoxy)-, monomethyl ester, (2R)-(188407-84-3)
• EPA Substance Registry System: Propanedioic acid, methyl(4-methyl-2-nitrophenoxy)-, monomethyl ester, (2R)-(188407-84-3)

Safety Data

• Hazardous Substances Data: 188407-84-3(Hazardous Substances Data)

Upstream product

• 29653-28-9 dimethyl 2-bromo-2-methylmalonate 
• 609-02-9 methyl-malonic acid dimethylester 
• 188407-71-8 2-Methyl-2-(4-methyl-2-nitro-phenoxy)-malonic acid dimethyl ester 

Downstream Products

• 208342-05-6 (R)-(-)-methyl 2-carbamoyl-2-(4-methyl-2-nitrophenoxy)propanoate 
• 377778-86-4 benzyl (2S)-1-[(2R)-3-methoxy-2-methyl-2-(4-methyl-2-nitrophenoxy)-3-oxopropanoyl]-2-pyrrolidinecarboxylate 

Relevant articles and documents

Stereoselective synthesis of (R)- and (S)-2-methyl-3-oxo-3,4-dihydro- 2H-1,4-benzoxazine-2-carboxylic acids, -carboxylates and -carboxamides

(R)-Monomethyl 2-methyl-2-(2-nitrophenoxy)malonates obtained by PLE catalyzed hydrolysis of the corresponding dimethyl malonates undergo solvent- dependent enantioselective cyclization to afford (R)-methyl 2-methyl-3-oxo- 3,4-dihydro-2H-1,4-benzoxazine-2-