188447-84-9Relevant academic research and scientific papers
Asymmetric thio-Michael/nucleophilic addition domino reaction with chiral N-sulfinimines
Kamimura, Akio,Okawa, Hidenori,Morisaki, Yuki,Ishikawa, Shingo,Uno, Hidemitsu
, p. 3569 - 3572 (2008/02/04)
(Chemical Equation Presented) Optically active N-sulfinimines underwent stereoselective Michael/nucleophilic addition domino reaction triggered by magnesium thiolate to give α-phenylthiomethyl-β-(N-sulfinylamino) esters in high diastereomeric excess. The
Synthesis of enantiopure sulfinimines (Thiooxime S-oxides) catalyzed by Yb(OTf)3 from p-toluenesulfinamide and aldehydes in mild reaction conditions
Jiang, Zhi-Yong,Chan,Lee
, p. 1081 - 1083 (2007/10/03)
(Chemical Equation Presented) Enantiomerically pure sulfinimines as important building blocks in the asymmetric synthesis of amine derivatives are prepared in good to excellent yields from chiral p-toluene-sulfinamide with aromatic, heteroaromatic, and al
Asymmetric synthesis of sulfinimines: Chiral ammonia imine synthons
Davis, Franklin A.,Reddy, Rajarathnam E.,Szewczyk, Joanna M.,Portonovo, Padma S.
, p. 6229 - 6232 (2007/10/02)
Two Andersen-type procedures for the preparation of enantiopure sulfinimines 1 (R=H) in better than 95% ee from nitriles and aldehydes are described.
