188482-95-3Relevant academic research and scientific papers
New tetradentate Schiff bases, their oxovanadium(IV) complexes, and some complexes of bidentate Schiff bases with vanadium(III)
Choudhary, Nosheen,Hughes, David L.,Kleinkes, Uwe,Larkworthy, Leslie F.,Leigh, G. Jeffery,Maiwald, Michael,Marmion, Celine J.,Sanders, J. Roger,Smith, Gallenius W.,Sudbrake, Claas
, p. 1517 - 1528 (2008/10/09)
New vanadyl(IV) complexes of tetradentate Schiff-base dianions containing one, two or three carbon atoms between the two iminato-nitrogen atoms are described. The compounds are either mononuclear or polymeric, as shown by the value of v(V = O), and depending upon the Schiff-base dianion. There is no evidence for electron delocalization along the polymeric chains. Some vanadium(III) complexes of bidentate Schiff-base monoanions have also been isolated; the crystal structure of [VO(2-OC6H4CHNH)2] and preliminary data on the structure of [V(Prhap)3] · toluene [HPrhap = 2-HOC6H4C(Me)NCH2CH2Me] are reported.
