188530-99-6Relevant academic research and scientific papers
Synthesis and Reactions of 3-(Nosyloxy)-2-keto Esters
Hoffman, Robert V.,Catherine Johnson,Okonya, John F.
, p. 2458 - 2465 (2007/10/03)
A series of 3-(nosyloxy)-2-keto esters 7a-j were prepared from the corresponding α-keto esters by conversion to the trimethylsilyl enol ether and reaction with p-nitrobenzenesulfonyl peroxide. Conversion of these materials to 1,2,3-trifunctionalized compounds is described, and comparison of their properties with isomeric 2-(nosyloxy)-3-keto esters is discussed.
