188538-46-7Relevant academic research and scientific papers
Utilization of the Phenylthio Substituent as a Multipurpose Synthetic Tool. Direct Application to the Enantioselective Construction of (-)-Salsolene Oxide
Paquette, Leo A.,Sun, Li-Qiang,Watson, Timothy J. N.,Friedrich, Dirk,Freeman, Brett T.
, p. 8155 - 8161 (2007/10/03)
The architecturally unprecedented sesquiterpene (-)-salsolene oxide (1) has been synthesized in enantioselective fashion from (R)-(-)-carvone. Generation of the phenylthio-substituted vinyl ketene 4 is followed by intramolecular cyclization to the functio
