18858-60-1Relevant academic research and scientific papers
An efficient method for the synthesis of symmetrical disiloxanes from alkoxysilanes using Meerwein's reagent
Jorapur, Yogesh R.,Shimada, Toyoshi
supporting information; experimental part, p. 1633 - 1638 (2012/08/07)
We report here a new and efficient route to symmetrical disiloxanes from their corresponding alkoxysilanes using Meerwein's reagent as mediator and potassium carbonate as additive under mild reaction conditions in acetonitrile. Our methodology is very simple, economic, and high yielding. We have also proposed a reaction mechanism with the plausible silyloxonium intermediates. Georg Thieme Verlag Stuttgart · New York.
