188583-25-7

Upstream product

• 2186-92-7 p-Anisaldehyde dimethyl acetal 
• 188583-24-6 phenyl 2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-1-thio-β-D-glucopyranoside 
• 187022-49-7 (2R,3S,4R,5R,6S)-2-(acetoxymethyl)-6-(phenylthio)-5-(((2,2,2-trichloroethoxy)carbonyl)amino)tetrahydro-2H-pyran-3,4-diyl diacetate 
• 122210-01-9 1,3,4,6-tetra-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-D-glucopyranose 
• 108-98-5 thiophenol 

Downstream Products

• 263010-65-7 phenyl 2-deoxy-4,6-O-p-methoxybenzylidene-3-O-(tetradecanoyl)-1-thio-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranoside 
• 188583-31-5 (S)-4-[(2R,3R,4R,5S,6R)-3-Amino-6-benzyloxymethoxymethyl-5-(diphenoxy-phosphoryloxy)-4-hydroxy-tetrahydro-pyran-2-yloxy]-2-tetradecanoylamino-butyric acid benzyl ester 
• 188583-28-0 phenyl 6-O-benzyloxymethyl-2-deoxy-1-thio-3-O-(2,2,2-trichloroethoxycarbonyl)-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranoside 
• 188583-27-9 phenyl 2-deoxy-1-thio-3-O-(2,2,2-trichloroethoxycarbonyl)-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranoside 
• 263010-67-9 N-tetradecanoyl-O-[4,6-di-O-acetyl-2-deoxy-3-O-tetradecanoyl-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranosyl]-L-serine benzyl ester 
• 263010-66-8 phenyl 4,6-di-O-acetyl-2-deoxy-3-O-(tetradecanoyl)-1-thio-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranoside 
• 888017-27-4 Tetradecanoic acid (2R,3S,4R,5R,6S)-3-hydroxy-2-hydroxymethyl-6-phenylsulfanyl-5-(2,2,2-trichloro-ethoxycarbonylamino)-tetrahydro-pyran-4-yl ester 
• 188583-26-8 phenyl 2-deoxy-4,6-O-p-methoxybenzylidene-1-thio-3-O-(2,2,2-trichloroethoxycarbonyl)-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranoside 

Relevant academic research and scientific papers

Copper(II) triflate: A versatile catalyst for the one-pot preparation of orthogonally protected glycosides

The development of general and expedient methodologies for the preparation of orthogonally protected glycoside building blocks is essential for the efficient synthesis of complex oligosaccharides. Herein, we describe a new approach that uses copper(II) triflate as a versatile catalyst for the one-pot preparation of orthogonal protected thio- and O-glycosides from the corresponding unprotected counterparts. The conditions are mild, easy to handle and applicable to two and three one-pot tandem transformations, which include arylidene acetalation, esterification, regioselective reductive acetal ring opening, glycosylation and silylation processes. Copyright

Lipid A and related compounds. XXXII. Synthesis of biologically active N-acylated L-homoserine-containing D-glucosamine-4-phosphate derivatives structurally related to lipid A

New N-acylated L-homoserine-containing non-phosphorylated and phosphorylated D-glucosamine derivatives were synthesized as mimicks of lipid A disaccharide. Some of the synthesized compounds exhibited mitogenic activity and nitric oxide (NO) productivity.