188595-15-5Relevant academic research and scientific papers
Synthesis and characterization of achiral bent-core liquid crystalline molecules containing salicylaldimine-based with a wide temperature range of SmCP phase
Liao, Chien-Tung,Liu, Jung-Yo,Zou, Sing-Fang,Wu, Nien-Chieh,Wu, Zheng-Long,Lee, Jiunn-Yih
, p. 124 - 133 (2010)
The design and synthesis of a series bent-core materials base on a 3,4'-biphenyldiol central core containing salicylaldimine-based and two terminal tetradecyloxy tails are reported. In addition, the effects of lateral substituents (R = F and Cl) at the biphenyl core into 3'-position are examined. These substituents have a strong influence in reducing the clearing temperatures and increasing temperature range of SmCP phase. Upon cooling process the isotropic liquid, compound SB-Cl exhibits the lowest clearing transition temperature of 180 oC and the widest SmCP phase range of 129 °C. The mesophase behaviour were investigated by polarizing optical microscopy (POM), differential scanning calorimetry (DSC), X-ray diffraction (XRD), and electro-optical (EO) measurements in the mesophase temperature range.
POLYMERIZABLE CINNAMATE ESTER DERIVATIVE MANUFACTURING METHOD
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Paragraph 0153-0154; 0156, (2020/08/15)
PROBLEM TO BE SOLVED: To provide a method of manufacturing a polymerizable cinnamate ester derivative that can be added to a liquid crystal composition in producing a TFT liquid crystal display element so as to reduce burning in the display element; a method of manufacturing a polymerizable composition containing the polymerizable cinnamate ester derivative; and a method of manufacturing a liquid crystal display element by polymerizing the polymerizable composition. SOLUTION: A method of manufacturing a compound represented by the specified general formula (III) includes reacting a compound represented by the specified general formula (I) with a compound represented by the specified general formula (II). SELECTED DRAWING: None COPYRIGHT: (C)2020,JPOandINPIT
Diacrylate monomers and polymers formed therefrom
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Example 1, (2010/01/31)
Rigid-rod monomers and polymers are provided for use in applications such as rapid prototyping, composites and adhesives. The monomers can be photocured through the end groups and then thermally post cured through the acetylene groups. The result is a hig
POLYMERIZABLE COMPOSITION SHOWING LIQUID-CRYSTAL PHASE AND OPTICALLY ANISOTROPIC OBJECT MADE WITH THE SAME
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Page 51, 55, (2008/06/13)
An object of the present invention is to provide a polymerizable liquid crystal composition incorporating a polymerizable liquid crystal compound which displays a low nematic phase temperature, displays excellent compatibility with other polymerizable liquid crystal compounds, and furthermore yields a product following polymerization, of good transparency and high mechanical strength. A polymerizable composition is provided which displays a liquid crystal phase, and moreover incorporates a liquid crystal backbone with two or more ring structures and a compound with a partial structure represented by the general formulaP-S-A-D-E- [wherein P1 represents a polymerizable functional group; S1 represents -(CH2)w-, - O(CH2)w-, -(CH2)wO-, -(CH2)wC(=O)O-, -(CH2)wOC(=O)-, -C(=O)O(CH2)w- or - OC(=O)(CH2)w- (w: 1 to 20); A1 and E1 each represent a hydrocarbon ring or a hetero ring, although E1 is a ring incorporated within the liquid crystal backbone; and D1 represents - C(=O)-O-(CH2)m-O-, -O(CH2)m-O-C(=O)-, -O-C(=O)-(CH2)m-O-, or -O(CH2)m-C(=O)-O- (m: 1 to 15)].
