188633-56-9Relevant academic research and scientific papers
The preparation of N-tert-butyloxycarbonyl-(Boc-)protected sulfoximines and sulfimines by an iron(II)-mediated nitrene transfer from BocN3 to sulfoxides and sulfides
Bach, Thorsten,Koerber, Christina
, p. 1033 - 1039 (1999)
The imidation of sulfides and sulfoxides to the corresponding sulfimides and sulfoximides was carried out with N-tert-butyloxycarbonyl azide (BocN3) in the presence of FeCl2. Sulfoxides 1 reacted at room temperature in CH2
Synthesis of pseudopeptides with sulfoximines as chiral backbone modifying elements
Bolm, Carsten,Moll, Guido,Kahmann, Jan D.
, p. 1118 - 1128 (2007/10/03)
The synthesis of pseudopeptides with a chiral α-sulfonimidoylcarboxy moiety in the backbone is described. Starting from readily available (Ss)-S-methyl S-phenyl sulfoximine and various cyclic and acyclic α-amino acids the desired products are o
Sulfoximines in pseudopeptides
Bolm, Carsten,Kahmann, Jan D.,Moll, Guido
, p. 1169 - 1172 (2007/10/03)
Syntheses of sulfoximine-containing pseudopeptides of type 2 are reported. Intramolecurar hydrogen bonds have been revealed by NMR spectroscopy.
