18866-47-2Relevant articles and documents
Synthesis, characterization, and non-isothermal curing kinetics of two silicon-containing arylacetylenic monomers
Tan, Dexin,Shi, Tiejun,Li, Zhong
, p. 831 - 845 (2011)
Vinyltri(phenylethynyl)silane ((ph-C≡C)3-Si-C=CH 2; VTPES) and phenyltri(phenylethynyl)silane ((ph-C≡C) 3-Si-ph; PTPES) were synthesized by Grignard reaction. Their molecular structures were characterized by means of
Alkynylsilanes and alkynyl(vinyl)silanes. synthesis, molecular structures and multinuclear magnetic resonance study
Wrackmeyer, Bernd,Khan, Ezzat,Bayer, Stefan,Tok, Oleg L.,Klimkina, Elena V.,Milius, Wolfgang,Kempe, Rhett
experimental part, p. 725 - 744 (2011/01/11)
Alkynylsilanes bearing one to four alkynyl groups at silicon, with organyl groups (Me, Ph, Vin), H, Cl at silicon, and with substituents H, nBu, tBu, Ph, C6H4-4-Me, 3-thienyl, CH 2NMe2 at t
Copper(I) chloride catalyzed cross-dehydrocoupling reactions between silanes and ethynyl compounds. A new method for the copolymerization of silanes and alkynes
Liu, Hua Qin,Harrod, John F.
, p. 1100 - 1105 (2007/10/02)
In the presence of an amine, copper(I) chloride is an effective catalyst for the cross-dehydrocoupling of silanes with alkynes.The reactions proceed at useful rates above 100 deg C, but rates drop dramatically on going from 1o to 2o