188779-01-3

Upstream product

• 134039-09-1 methyl 2,6-di-O-benzyl-5-C-methoxy-β-D-galactopyranoside 
• 134039-06-8 methyl 2,6-di-O-benzyl-4-deoxy-α-L-threo-hex-4-enopyranoside 

Downstream Products

• 1438394-13-8 C₂₀H₂₂O₆ 
• 283176-83-0 2,4-di-O-benzyl-2L-(2,3,5,6/4)-pentahydroxy-cyclohexanone 
• 188779-05-7 2,6-di-O-benzyl-1,5-dideoxy-1,5-imino-N-methyl-D-galactitol 
• 283586-00-5 1D-2,6-di-O-benzyl-epi-inositol 
• 60802-59-7 (2R,3R,4S,5S,6S)-2,3,4,5,6-Pentahydroxy-cyclohexanone 
• 488-58-4 epi-Inositol 
• 188779-02-4 2,6-di-O-benzyl-1,5-dideoxy-1,5-imino-D-galactitol 

Relevant academic research and scientific papers

A new method for the synthesis of carba-sugar enones (gabosines) using a mercury(II)-mediated opening of 4,5-cyclopropanated pyranosides as the key-step

The stereoselective transformation of the cyclopropyl derivative 2, stereoselectively obtained with the Simmons-Smith reaction of methyl 2,6-di-O-benzyl-α-l-threo-hex-4-enopyranoside (1), into gabosines and deoxy-carbahexoses is described. The treatment o