188781-60-4Relevant academic research and scientific papers
Acyclic diyne metathesis (ADIMET), an efficient route to poly(phenylene)ethynylenes (PPEs) and nonconjugated polyalkynylenes of high molecular weight
Weiss,Michel,Auth,Bunz,Mangel,Mullen
, p. 506 - 509 (1997)
Conjugated and nonconjugated diynes can be readily converted to poly(phenylene)-ethynylene derivatives and polyalkylenes by acyclic diyne metathesis. The catalyst for these condensation reactions is [(tBuO)3W≡CtBu], and they proceed with cleava
Synthesis of poly(2,5-thienyleneethynylene)s by alkyne metathesis
Zhang, Wei,Moore, Jeffrey S.
, p. 3973 - 3975 (2007/10/03)
The formation of high molecular weight products by the synthesis of poly(2,5-trienylene ethylene) from alkyne metathesis was discussed. Coupling reactions of diethynylated aromatics with dihalogenated arenes was performed in the synthesis process using Sh
