188783-73-5Relevant academic research and scientific papers
The synthesis of N-acetyl-β-L-fucosamine-1-phosphate and uridine 5′-diphospho-N-acetyl-β-L-fucosamine
Illarionov,Torgov,Hancock,Shibaev
, p. 1891 - 1894 (2000)
Uridine 5′-(2-acetamido-2,6-dideoxy-β-L-galactopyranosyl) diphosphate (uridine 5′-diphospho-N-acetyl-β-L-fucosamine) was synthesized. The key intermediate, 3,4-di-O-acetyl-2-azido-2,6-dideoxy-β-L-galactopyranosyl dibenzyl phosphate, was prepared by a prev
Synthesis of glycosyl phosphates from acetylated glycosyl nitrates
Illarionov, Petr A.,Torgov, Vladimir I.,Hancock, Ian C.,Shibaev, Vladimir N.
, p. 4247 - 4250 (2007/10/03)
Acetylated α-glycosyl nitrates were efficiently converted under mild conditions into protected β-glycosyl phosphates by treatment with cesium dibenzyl phosphate or into thermodynamically more stable α-glycosyl phosphate derivatives upon interaction with cesium diphenyl phosphate. These reactions were found to be applicable both to 2-azido-2,6-dideoxy- and 2-azido-2-deoxygalactopyranosyl nitrates as well as to 6-deoxygalactopyranosyl and galactopyranosyl derivatives.
