18888-79-4Relevant academic research and scientific papers
Synthesis of selectively deuterated fulvenes and indenes from enediynes
Peabody, Scott W.,Breiner, Boris,Kovalenko, Serguei V.,Patil, Satish,Alabugin, Igor V.
, p. 218 - 221 (2005)
The method for producing selectively deuterated fulvenes and indenes from enediynes was described. Fulvenes and benzofulvenes were used as a key intermediates in the total synthesis of several natural products. Subsequent destannylation were achieved usin
5-Exo-dig radical cyclization of enediynes: The first synthesis of tin-substituted benzofulvenes
Kovalenko, Serguei V.,Peabody, Scott,Manoharan, Mariappan,Clark, Ronald J.,Alabugin, Igor V.
, p. 2457 - 2460 (2007/10/03)
(Equation Presented) Bu3Sn-mediated 5-exo-dig radical cyclization of diaryl enediynes provides a mild and efficient approach to tin-substituted fulvenes. Further synthetic opportunities opened by this process and general factors responsible for
Photochemistry of 2-Vinylstilbene, 1,2-Distyrylbenzene, and 2,2'-Distyrylbiphenyl Absorbed on Silica Gel. Influence of Ground-State Conformers on Formation of Photoproducts
Tol, Arie J. W.,Laarhoven, Wim H.
, p. 1663 - 1668 (2007/10/02)
Irradiation of 2-vinylstilbene (1) absorbed on silica gel gives rise to several products.In addition to exo- and endo-5-phenylbenzobicyclohex-2-enes (2 and 3) (the sole products formed in solution) derivatives of naphthalene and of indene are forme
