189076-44-6

Basic information

• Product Name: Oxirane, 2-(3-methyl-3-butenyl)-2-(1-methylethyl)- (9CI)
• Synonyms: Oxirane, 2-(3-methyl-3-butenyl)-2-(1-methylethyl)- (9CI)
• CAS NO: 189076-44-6
• Molecular Formula: C10H18O
• Molecular Weight: 154.24932
• Product Categories: ISOPROPYL
• Mol File: 189076-44-6.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Oxirane, 2-(3-methyl-3-butenyl)-2-(1-methylethyl)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Oxirane, 2-(3-methyl-3-butenyl)-2-(1-methylethyl)- (9CI)(189076-44-6)
• EPA Substance Registry System: Oxirane, 2-(3-methyl-3-butenyl)-2-(1-methylethyl)- (9CI)(189076-44-6)

Safety Data

• Hazardous Substances Data: 189076-44-6(Hazardous Substances Data)

Upstream product

• 593-71-5 Chloroiodomethane 
• 36584-59-5 2,6-dimethylhept-6-en-3-one 

Downstream Products

• 15356-70-4 menthol 
• 3623-52-7 isomenthol 
• 317801-55-1 cis-2-isopropyl-5-methylenecyclohexanol 
• 317801-55-1 trans-2-isopropyl-5-methylenecyclohexanol 

Relevant articles and documents

Organoaluminum-Promoted Cyclization of Olefinic Epoxides. a New and Stereoselective Approach to Cyclohexane Frameworks

A new, general synthetic method of six-membered carbocycles has been demonstrated, which involves the stereo-controlled cyclization of olefinic epoxides with methylaluminum bis(4-bromo-2,6-di-t-butylphenoxide) (MABR) via the epoxide rearrangement and subsequent intramolecular ene reaction with high stereoselectivity. This strategy is shown to be highly useful in the stereoselective synthesis of the basic skeleton of various terpenes.