1891-96-9Relevant articles and documents
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Schlosser,M.,Van Chau,L.
, p. 2595 - 2604 (1975)
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Copper(I)-catalyzed solvolysis of gem-chlorofluoro- and gem-bromofluorocyclopropanes. Preparation of 2-fluoroallylic ethers, esters and alcohols
Novikov, Maxim A.,Volchkov, Nikolai V.,Lipkind, Maria B.,Nefedov, Oleg M.
, p. 131 - 143 (2015/10/05)
Copper(I)-catalyzed solvolysis of gem-chlorofluoro- and gem-bromofluorocyclopropanes in MeOH, NaOAc/AcOH, NaOAc/DMF, HCO2Na/HCO2H or water/dioxane affords 2-fluoroallylic ethers, esters or alcohols in moderate to excellent yields. Th
CuCl-catalyzed isomerization of gem-Chlorofluoro-cyclopropanes into chlorofluoroalkenes
Volchkov, Nikolai V.,Novikov, Maksim A.,Lipkind, Mariya B.,Nefedov, Oleg M.
, p. 19 - 21 (2013/08/24)
CuCl-catalyzed isomerization of gem-chlorofluorocyclopropanes into chlorofluoroalkenes occurs as a result of the ring opening accompanied by the migration of chlorine atom. In the case of vinyl- or cyclopropyl-containing substrates, chlorofluoroalkadienes