189154-00-5Relevant academic research and scientific papers
Palladium-catalyzed enantioselective oxidation of chiral secondary alcohols: Access to both enantiomeric series
Ebner, David C.,Trend, Raissa M.,Genet, Cedric,McGrath, Matthew J.,O'Brien, Peter,Stoltz, Brian M.
, p. 6367 - 6370 (2008)
(Chemical Equation Presented) Rapid resolution: A new catalyst system for the oxidative kinetic resolution of secondary alcohols leads to dramatic rate increases. This system allows the use of a diamine to provide access to either enantiomer of a range of alcohols with good selectivity factors (see scheme). This method has been applied to the formal total synthesis of (-)-amurensinine.
