189184-89-2

Upstream product

• 79328-85-1 N-benzyloxycarbonyl-1,2-dihydropyridine 
• 189184-88-1 (1R,4R,7R)-7-((1S,2R,6S,7R)-7,10,10-Trimethyl-3-oxa-5-aza-tricyclo[5.2.1.0^2,6]dec-4-en-4-yl)-2-aza-bicyclo[2.2.2]oct-5-ene-2-carboxylic acid benzyl ester 
• 115-11-7 isobutene 

Downstream Products

• 189184-85-8 (1R,2R,3R,4R,5S)-3,4-Diacetoxy-5-[(benzyloxycarbonyl-methyl-amino)-methyl]-2-(4-methoxy-phenylsulfanyl)-cyclohexanecarboxylic acid methyl ester 
• 189184-84-7 (3S,4R,5S)-3,4-Diacetoxy-5-[(benzyloxycarbonyl-methyl-amino)-methyl]-cyclohex-1-enecarboxylic acid methyl ester 
• 189184-57-4 (3R,4R,5S)-5-[(Benzyloxycarbonyl-methyl-amino)-methyl]-4-hydroxy-3-prop-2-ynyloxy-cyclohex-1-enecarboxylic acid tert-butyl ester 
• 189184-53-0 (1S,5S,6R)-5-[(Benzyloxycarbonyl-methyl-amino)-methyl]-7-oxa-bicyclo[4.1.0]hept-2-ene-3-carboxylic acid tert-butyl ester 
• 189184-94-9 (3aS,7S,7aR)-7-[(Benzyl-methyl-amino)-methyl]-2,2-dimethyl-3a,6,7,7a-tetrahydro-benzo[1,3]dioxole-5-carboxylic acid tert-butyl ester 
• 189184-75-6 (3S,4R,5S)-5-[(Benzyloxycarbonyl-methyl-amino)-methyl]-3,4-dihydroxy-cyclohex-1-enecarboxylic acid methyl ester 
• 189184-81-4 (3S,4R,5S)-5-Dimethylaminomethyl-3,4-dihydroxy-cyclohex-1-enecarboxylic acid tert-butyl ester 
• 189184-72-3 (1S,4S,6R,7S,8R)-7,8-Dihydroxy-2-aza-bicyclo[2.2.2]octane-2,6-dicarboxylic acid 2-benzyl ester 6-tert-butyl ester 
• 189184-91-6 (R)-5-[(Benzyloxycarbonyl-methyl-amino)-methyl]-cyclohexa-1,3-dienecarboxylic acid tert-butyl ester 

Relevant academic research and scientific papers

New synthetic approaches to the oxahydrindane subunit of avermectins

Isoquinuclidine derivatives 9a, 9b, resulting from an asymmetric Diels-Alder cycloaddition, afforded, after a two step sequence of reactions, functionalized cyclohexenes 11 and 31 precursors of the oxahydrindane subunit of Avermectins.