18922-21-9Relevant articles and documents
CHLOROSULFONATION OF SOME COMPOUNDS CONTAINING TWO PHENYL RINGS
Cremlyn, Richard,Swinbourne, Frederick J.,Graham, Stephen,Lynch, John M.
, p. 121 - 134 (2007/10/02)
Diphenylmethane (1) and dibenzyl (17) reacted with chlorosulphonic acid to give the corresponding p,p'-disulphonyl chlorides (2,18).However, attempted chlorosulfonations of α-chloro-, αα'-dichlorodiphenylmethane, stilbene and 1,4-diphenylbutadiene were unsuccessful.Diphenylacetic acid reacted with chlorosulfonic acid to give a mixture of 4,4'-dichlorosulfonylbenzophenone (40) and α-chlorodiphenylmethane-4,4'-disulfonyl chloride (39).Benzilic acid (41) afforded 9-chlorofluorene-2,7-disulfonyl chloride (42), which with amines gave 3 different products according to the reaction conditions.Fluorene (53) and the 9-carboxylic acid (43) have been treated with chlorosulfonic acid.The various sulfonyl chlorides were converted into 43 derivatives for biocidal evaluation.Mechanistic interpretations for the reactions is included.
Bibenzyl-4-sulfonyl chloride
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, (2008/06/13)
Sulfone polymers are disclosed containing bibenzyl sulfone repeating units having the formula STR1 These polymers exhibit good mechanical properties, toughness, flexibility, thermal and chemical stability and can be heat processed, extruded, drawn or othe