18944-96-2

Upstream product

• 18933-64-7 Benzoic acid (2S,3S,4R,6S)-2-bromomethyl-4-hydroxy-6-methoxy-tetrahydro-pyran-3-yl ester 
• 18546-25-3 6-O-p-tolylsulfonyl-3,4-di-O-acetyl-D-glucal 
• 13322-79-7 (2R,3S,4R,6S)-6-Methoxy-2-methyl-tetrahydro-pyran-3,4-diol 
• 363134-99-0 diacetyl-d-glucal-6-bromohydrin 
• 99371-23-0 Methyl-3-O-<(tert-butyl)(dimethyl)silyl>-2,6-didesoxy-α-D-arabino-hexopyranosid 
• 86651-49-2 methyl 3,4-di-O-acetyl-2,6-dideoxy-α-D-arabino-hexopyranoside 
• 76739-66-7 3,4-di-O-acetyl-D-rhamnal 
• 2873-29-2 D-glucal triacetate 
• 381727-32-8 acetyl 4-O-benzoyl-3-O-tert-butyldimethylsilyl-2,6-dideoxy-2-iodo-α-D-manno-hexopyranose 
• 381727-35-1 methyl 4-O-benzoyl-3-O-tert-butyldimethylsilyl-2,6-dideoxy-2-iodo-α-D-manno-hexopyranoside 
• 120316-46-3 Benzoic acid (2R,3R,4R)-4-(tert-butyl-dimethyl-silanyloxy)-2-methyl-3,4-dihydro-2H-pyran-3-yl ester 
• 121352-11-2 methyl 4-O-benzoyl-2,6-dideoxy-3-O-(p-tolylsulfonyl)-α-D-arabino-hexopyranoside 

Downstream Products

• 111375-91-8 Benzoic acid (2R,3R,4R,6S)-6-methoxy-2-methyl-4-trifluoromethanesulfonyloxy-tetrahydro-pyran-3-yl ester 
• 137333-07-4 methyl 4-O-benzoyl-3-O-(2,3,6-trideoxy-3-C-methyl-4-O-methyl-3-nitro-α-L-arabino-hexopyranosyl)-2,6-dideoxy-α-D-arabino-hexopyranoside 
• 72062-88-5 Benzoic acid (2R,3R,4R,6S)-4-methanesulfonyloxy-6-methoxy-2-methyl-tetrahydro-pyran-3-yl ester 
• 121352-11-2 methyl 4-O-benzoyl-2,6-dideoxy-3-O-(p-tolylsulfonyl)-α-D-arabino-hexopyranoside 
• 381727-55-5 C₃₃H₄₅IO₉Si 
• 381727-56-6 C₃₃H₄₆O₉Si 
• 381727-51-1 C₂₇H₃₂O₉ 
• 32476-34-9 Methyl 3,4-di-O-benzoyl-2,6-dideoxy-α-D-arabino-hexopyranoside 

Relevant academic research and scientific papers

Direct and stereoselective synthesis of β-linked 2,6- deoxyoligosaccharides

(Chemical Equation Presented) Short and sweet: Glycosidation of 2-deoxyglycosyl imidates with I2 as shown in the scheme (Bn = benzyl, Bz = benzoyl, MS = molecular sieves) proceeds smoothly to provide the corresponding β-linked 2-deoxyglycosides

The first polymer-assisted solution-phase synthesis of deoxyglycosides

Figure presented A glycosylation protocol for the synthesis of 2-deoxyglycosides has been developed which is based on the use of polymer-bound reagents. Glycals are transformed into 2-iodoglycosyl acetates using polymer-bound bis(acetoxy)iodate(I) complex

Photoremovable Hydroxyl Group Protection. Use of the p-Tolylsulfonyl Protecting Group in β-Disaccharide Synthesis

The p-tolylsulfonyl group has been shown to a photoremovable group effective for protection of carbohydrates during disaccharide synthesis.The formation of the versatile, p-tolylsulfonyl-protected disaccharide 13 methyl 3-O-(4-O-benzoyl-3-O-benzyl-2,6-di