189507-89-9Relevant academic research and scientific papers
Stereospecific synthesis of methyl vinyl ketones
Chamakh,M'hirsi,Amri
, p. 1157 - 1163 (1997)
A stereospecific synthesis of enones 3 by coupling reaction of α-acetoxy alkyl methyl vinyl ketones 2 and Gilman or Grignard reagents in the presence of a catalytic amount of copper(I) salt at low temperature, is described.
Rhodium-catalyzed formation of stereocontrolled trisubstituted alkenes from Baylis-Hillman adducts
Gendrineau, Thomas,Demoulin, Nicolas,Navarre, Laure,Genet, Jean-Pierre,Darses, Sylvain
supporting information; experimental part, p. 4710 - 4715 (2009/12/30)
We report here efficient and general conditions for the formation of stereodefined trisubstituted alkenes using the rhodium-catalyzed reaction of unactivated Baylis-Hillman adducts with either organoboronic acids and potassium trifluoro(organo)borates. Th
