189632-47-1Relevant academic research and scientific papers
New type of polysilanes: Poly(1,1-silole)s
Tamao, Kohei,Yamaguchi, Shigehiro
, p. 5 - 11 (2007/10/03)
Poly(1,1-silole)s were synthesized for the first time in 1999, by us and by West and his coworkers, as a new type of polysilane which is expected to have a low-lying LUMO due to the σ*-π*conjugation characteristic of the silole ring. Summarized herein are the development of new synthetic methodologies and the structural aspects, photophysical properties and a unique reactivity of the resulting oligo- and poly(1,1-silole)s.
Silacyclopentadiene derivative
-
, (2008/06/13)
The present invention provides a silacyclopentadiene derivative represented by the following Formula (1): STR1 wherein X1 and Y1 represent independently a halogen atom, an amino group, a hydroxyl group, or an amino group or a hydroxy
