189679-99-0Relevant academic research and scientific papers
Preparation and characterization of methyl 11-amino-(N-P-toluenesulfonyl)-9-E-octadecenoate and methyl 8-amino-(N-P-toluenesulfonyl)-9-E-octadecenoate
Herron, Barry F.,Bagby, Marvin O.,Isbell, Terry A.,Byrdwell, Wm Craig,Plattner, Ron,Weisleder, David
, p. 229 - 234 (2007/10/03)
Allylic amination of methyl oleate with bis(N-p- toluenesulfonyl) sulfodiimide results in a mixture of methyl 11- amino-(N-p-toluenesulfonyl)-9-E-octadecenoate and methyl 8- amino-(N-p-toluerfesulfonyl)-9-E-octadecenoate in 58% yield. These novel products were isolated and characterized by nuclear magnetic resonance, infrared spectroscopy, mass spectrometry, and melting point. The reaction was analyzed by high- performance liquid chromatography and thin-layer chromatography.
