189683-17-8Relevant articles and documents
Use of cyclic sulfamidates derived from D-allosamine in nucleophilic displacements: Scope and limitations
Aguilera, Begona,Fernandez-Mayoralas, Alfonso,Jaramillo, Carlos
, p. 5863 - 5876 (2007/10/03)
A cyclic 2,3-sulfamidate derived from N-acetyl-D-allosamine has been treated with a variety of S-. N-, O-. and C-nucleophiles, leading to nucleophilic displacement at C-3, elimination, or deacetylation reactions depending on the type of nucleophile used. Nucleophilic displacement is achieved with thio-nucleophiles and NaN3. allowing the preparation of 3-thio- or 3-azido glucosamine derivatives difficult to obtain by use of sulfonates.