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Pd(CO)(C10H8N)(SP(C6H5)3)(1+)*ClO4(1-) = [Pd(CO)(C10H8N)(SP(C6H5)3)]ClO4 is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

189695-53-2

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189695-53-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 189695-53-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,8,9,6,9 and 5 respectively; the second part has 2 digits, 5 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 189695-53:
(8*1)+(7*8)+(6*9)+(5*6)+(4*9)+(3*5)+(2*5)+(1*3)=212
212 % 10 = 2
So 189695-53-2 is a valid CAS Registry Number.

189695-53-2Downstream Products

189695-53-2Relevant academic research and scientific papers

Neutral and cationic monocarbonyl derivatives of palladium(II). X-ray crystal structure of [Pd(8-mq)(CO)(SPPh3)]ClO4

Ara, Irene,Fornies, Juan,Navarro, Rafael,Sicilia, Violeta,Urriolabeitia, Esteban P.

, p. 1963 - 1970 (2008/10/09)

Carbonylation of [Pd(8-mq)(OCMe2)x]ClO4 (8-mq = 8-quinolylmethyl-C,N) in CH2Cl2/Me2CO at low temperature gave [Pd(8-mq)(OClO3)(CO)]. Reactions of [Pd(8-mq)(OClO3)(CO)] with anionic (Cl-, Bi-, I-) or neutral (SPPh3, SPMe2Ph) nucleophiles in a 1 : 1 molar ratio resulted in the displacement of the weakly coordinated OClO3- group and the formation of the corresponding neutral [Pd(8-mq)(X)(CO)] (X = Cl, Br, I) or cationic [Pd(8-mq)(CO)L]ClO4 (L = SPPh3, SPMe2Ph) carbonyl complexes. The cationic complexes, [Pd(8-mq)(CO)L]ClO4, were synthesized by the reaction of [Pd(8-mq)(OCIO3)(SPPh3)] or [Pd(8-mq)(μ-SPMe2Ph)]2(ClO4)2 with CO. The X-ray structure of a cationic palladium carbonyl derivative, [Pd(8-mq) (CO)(SPPh3)]ClO4, is reported.

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