18977-34-9

Basic information

• Product Name: 2,6-Bis(1-naphtylmethylene)cyclohexanone
• Synonyms: 2,6-Bis(1-naphtylmethylene)cyclohexan-1-one;2,6-Bis(1-naphtylmethylene)cyclohexanone;(2E,6Z)-2,6-bis(naphthalen-1-ylmethylidene)cyclohexan-1-one
• CAS NO: 18977-34-9
• Molecular Formula: C28H22O
• Molecular Weight: 374.47
• Mol File: 18977-34-9.mol
• Article Data: 3

Chemical Properties

• Melting Point: 208-209 °C(Solv: N,N-dimethylformamide (68-12-2))
• Boiling Point: 625.7±55.0 °C(Predicted)
• Appearance: /
• Density: 1.220±0.06 g/cm3(Predicted)
• CAS DataBase Reference: 2,6-Bis(1-naphtylmethylene)cyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2,6-Bis(1-naphtylmethylene)cyclohexanone(18977-34-9)
• EPA Substance Registry System: 2,6-Bis(1-naphtylmethylene)cyclohexanone(18977-34-9)

Safety Data

• Hazardous Substances Data: 18977-34-9(Hazardous Substances Data)

Upstream product

• 108-94-1 cyclohexanone 
• 66-77-3 1-naphthaldehyde 

Relevant articles and documents

Chemoselective Claisen-Schmidt bis-substitutional condensation catalyzed by an alkoxy-bridged dinuclear Ti(IV) cluster

The highly efficient and chemoselective α,α′-bis-substitution of alkanones is important in organic synthesis. Herein, a dimeric titanium cluster, Ti2Cl2(OPri)6·2HOPri (Ti2), is used in the Claisen-Schmidt condensation reaction, for the selectively activation of symmetrical ketones containing α,α′-methylene groups and production of α,α′-bis-substituted alkanones in high efficiency and chemoselectivity. The high efficiency and chemoselectivity can be extended to a variety of typical alkanones and aromatic aldehydes. Both of the oxo-bridged dimeric motif of Ti2 and the ionic Ti-Cl bond are responsible for the high efficiency and chemoselectivity.

New Aziridines and Pyrazolines Derived from Diarylidenecycloalkanones

A number of diarylidenecycloalkanones (I and II) have been prepared by the condensation of cycloalkanones with different aromatic aldehydes.Treatment of I and II with bromine gives the corresponding tetrabromides (III and IV).Compounds III react with meth