189949-30-2Relevant articles and documents
α,α-Difluoroallyl carbanion: Indium-mediation in its facile coupling with aldehydes
Kirihara, Masayuki,Takuwa, Tomofumi,Takizawa, Shinobu,Momose, Takefumi
, p. 2853 - 2854 (1997)
Indium-mediated coupling of aldehydes with 3-bromo-3,3-difluoropropene gives 1-substituted-2,2-difluorobut-3-en-1-ols in high yields at room temperature. The coupling takes place at the gem-difluorocarbon selectively. Ketones are inert under the condition