189949-30-2Relevant academic research and scientific papers
α,α-Difluoroallyl carbanion: Indium-mediation in its facile coupling with aldehydes
Kirihara, Masayuki,Takuwa, Tomofumi,Takizawa, Shinobu,Momose, Takefumi
, p. 2853 - 2854 (1997)
Indium-mediated coupling of aldehydes with 3-bromo-3,3-difluoropropene gives 1-substituted-2,2-difluorobut-3-en-1-ols in high yields at room temperature. The coupling takes place at the gem-difluorocarbon selectively. Ketones are inert under the condition
Indium-mediated reaction of 3-bromo-3,3-difluoropropene and bromodifluoromethylacetylene derivatives with aldehydes
Kirihara, Masayuki,Takuwa, Tomofumi,Takizawa, Shinobu,Momose, Takefumi,Nemoto, Hideo
, p. 8275 - 8280 (2007/10/03)
Aldehydes reacted with 3-bromo-3,3-difluoropropene at the α-position in the presence of indium to afford 1-substituted-2,2-difluorobut-3-en-1-ols. Ketones and other electrophiles are inert under the examined conditions. The reaction of bromodifluoromethyl
