190014-74-5

Basic information

• Product Name: 2H-Pyran-2-methanol,6-ethoxytetrahydro-3-methyl-,acetate,(2S,3S)-[partial]-(9CI)
• Synonyms: 2H-Pyran-2-methanol,6-ethoxytetrahydro-3-methyl-,acetate,(2S,3S)-[partial]-(9CI)
• CAS NO: 190014-74-5
• Molecular Formula: C₁₁H₂₀O₄
• Molecular Weight: 216.2741
• Product Categories: ETHOXY
• Mol File: 190014-74-5.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2H-Pyran-2-methanol,6-ethoxytetrahydro-3-methyl-,acetate,(2S,3S)-[partial]-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 2H-Pyran-2-methanol,6-ethoxytetrahydro-3-methyl-,acetate,(2S,3S)-[partial]-(9CI)(190014-74-5)
• EPA Substance Registry System: 2H-Pyran-2-methanol,6-ethoxytetrahydro-3-methyl-,acetate,(2S,3S)-[partial]-(9CI)(190014-74-5)

Safety Data

• Hazardous Substances Data: 190014-74-5(Hazardous Substances Data)

Upstream product

• 64-17-5 ethanol 
• 98815-75-9 6-O-acetyl-1,5-anhydro-2,3,4-trideoxy-4-C-methyl-D-erythro-hex-1-enitol 
• 168333-78-6 [(1S,2S,5R)-2-Methyl-6,8-dioxa-bicyclo[3.2.1]oct-(4E)-ylidene]-hydrazine 
• 168333-79-7 ((2S,3S)-3-Methyl-3,4-dihydro-2H-pyran-2-yl)-methanol 

Downstream Products

• 189832-20-0 [(2S,3S,6S)-6-((Z)-2-Benzenesulfonyl-2-triethylsilanyl-vinyl)-3-methyl-tetrahydro-pyran-2-yl]-methanol 
• 168608-75-1 (2R,3S,6S)-1-Benzenesulfonyl-2,6-dimethyl-oct-7-en-3-ol 
• 189832-21-1 [(2S,3S,6S)-6-((R)-2-Benzenesulfonyl-1-methyl-ethyl)-3-methyl-tetrahydro-pyran-2-yl]-methanol 
• 189832-22-2 (2S,3S,6S)-6-((R)-2-Benzenesulfonyl-1-methyl-ethyl)-2-iodomethyl-3-methyl-tetrahydro-pyran 
• 189832-19-7 [(2S,3S,6S)-3-Methyl-6-((Z)-2-phenylsulfanyl-2-triethylsilanyl-vinyl)-tetrahydro-pyran-2-yl]-methanol 
• 168333-95-7 (2S,3S,6S)-6-((Z)-2-Benzenesulfonyl-2-triethylsilanyl-vinyl)-2-(tert-butyl-dimethyl-silanyloxymethyl)-3-methyl-tetrahydro-pyran 

Relevant articles and documents

Synthetic studies on tautomycin synthesis of segment C

Synthesis of Segment C of tautomycin was accomplished from two D-sugar derivatives. Pseudoenantiomeric heteroconjugate addition strategy allowed stereocontrolled synthesis of Sub-segment C-l. Sub-segment C-2 and its three diastereoisomers have been synthesized through heteroconjugate addition strategy and Mitsunobu reaction, Sub segment C-1 (epoxide electrophile) and C2 (sulfone carbanion) were coupled in the presence of boron trifluoride etherate (BF3·OEt2) to furnish Segment C.