190075-72-0Relevant academic research and scientific papers
Anthracenic and naphthalenic vic-diepoxides. A new kind of isomerization going through fragmentation
Rigaudy, Jean,Lachgar, Mohamed
, p. 2267 - 2270 (2007/10/03)
When treated with Lewis acids in an anhydrous medium, syn and anti anthracenic and naphthalenic vic-diepoxides 2 and 3 rearrange more or less completely to acyl-benzo or naphthopyrans 1. This rearrangement, competing with more classical ones, appears to i
Photochemical transformations of endoperoxides derived from polycyclic aromatic hydrocarbons, VI. Photo-isomerization of 1,4-endoperoxides and of 1,2,3,4-diepoxides derived from 1,4-dimethylanthracenes
Rigaudy, J.,Caspar, A.,Lachgar, M.,Maurette, D.,Chassagnard, C.
, p. 16 - 24 (2007/10/02)
By photolysis at long wavelenghts, 1,4-endoperoxides, 2a,b of 1,4-dimethylanthracenes, 3a,b, isomerized to 1,2;3,4-diepoxides, 1a,b.When irradiated at shorter wavelengths, these compounds led to 3,4-epoxyanthracen-2(1H)-ones, 4a,b, which themselves photo-
