19009-48-4Relevant academic research and scientific papers
ADDITION RADICALAIRE DU PROPANAL A DIVERS ALCENES ET CYCLENES : ASPECTS STERIQUES ET POLAIRES
Tabbaa, I.,Cazaux, M.,Lalande, R.
, p. 1011 - 1018 (2007/10/02)
Free radical addition of propanal to double bonds, initiated by benzoyl peroxide, mainly leads to two adducts, an aldehyde and a ketone, when the double bond has a methylene group ; these results are explained in terms of polar effects in the free radical transfert reactions.When the double bond has no methylene group, only the ketonic adduct is obtained ; the steric effects in the free radical addition step explain these results.
