19023-27-9

Basic information

• Product Name: 1-[1,2,4,5-Tetrahydro-2-methyl-2-(1-naphtyl)-1,4-methano-3-benzoxepin-5-yl]ethanone
• Synonyms: 1-[1,2,4,5-Tetrahydro-2-methyl-2-(1-naphtyl)-1,4-methano-3-benzoxepin-5-yl]ethanone
• CAS NO: 19023-27-9
• Molecular Weight: 0
• Mol File: 19023-27-9.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1-[1,2,4,5-Tetrahydro-2-methyl-2-(1-naphtyl)-1,4-methano-3-benzoxepin-5-yl]ethanone(CAS DataBase Reference)
• NIST Chemistry Reference: 1-[1,2,4,5-Tetrahydro-2-methyl-2-(1-naphtyl)-1,4-methano-3-benzoxepin-5-yl]ethanone(19023-27-9)
• EPA Substance Registry System: 1-[1,2,4,5-Tetrahydro-2-methyl-2-(1-naphtyl)-1,4-methano-3-benzoxepin-5-yl]ethanone(19023-27-9)

Safety Data

• Hazardous Substances Data: 19023-27-9(Hazardous Substances Data)

Upstream product

• 941-98-0 1'-naphthacetophenone 

Relevant articles and documents

INFLUENCE OF THE NATURE OF THE BASE ELECTROLYTE ON THE REGIOSELECTIVITY OF THE CATHODIC HYDRODIMERIZATION OF 1-ACETYLNAPHTHALENE IN AN APROTIC MEDIUM

The electrolysis of 1-acetylnaphthalene at a controlled potential (DMF, Ba(ClO4)2) leads to the formation of 5-acetyl-1,2,4,5-tetrahydro-2-methyl-2-(1-naphthyl)-1,4-methano-3-benzoxepine (yield of 60percent); this is explained by the stabilization of the dimeric dianion of the "Head-tail" type by the Ba2+ cations.The formation of 2,3-dimethyl-2,3-di-(1-naphthyl)-butane-2,3-diol is observed with the acylotropic rearrangement of the intermediate anion, leading to 2-acetylnaphthalene, in the presenc of lithium cations.