190252-82-5Relevant academic research and scientific papers
Cyclopentadiene elimination reaction as a route to bis(neopenty)gallium phosphides. Crystal and molecular structures of [(Me3CCH2)2GaPEt2]2 and [(Me3CCH2)2GaP(C6H 11)2]2
Beachley Jr.,Maloney, John P.,Rogers, Robin D.
, p. 3267 - 3272 (1997)
The compound (Me3CCH2)2Ga(C5H5) has been observed to react at room temperature in pentane solution with HPEt2 and H2P(C6H11) to eliminate C5H6 and form [(Me3CCH2)2-GaPEt2]2 and [(Me3CCH2)2GaP(H)(C6H 11)]2, respectively. The additional new compound [(Me3CCH2)2GaP(C6H 11)2]2 was prepared by a metathetical reaction between Ga(CH2CMe3)2-Cl and LiP(C6H11)2 in diethyl ether. All three compounds were fully characterized in solution, whereas two of the three, [(Me3CCH2)2GaPEt2]2 and [(Me3CCH2)2GaP(C6H 11)2]2, were characterized by X-ray structural studies.
