190265-17-9Relevant academic research and scientific papers
Allylsilanes as carbon nucleophiles in the palladium-catalyzed 1,4-oxidation of conjugated dienes
Castano, Ana M.,Persson, B. Anders,Baeckvall, Jan-E.
, p. 482 - 490 (2007/10/03)
Palladium-catalyzed oxidation of cyclic 1,3-dienes 3,5,9,11, and 13, with an allylsilane group in the side chain, led to an intramolecular 1,4-syn-addition to the conjugated diene through a carbocyclization. Acyclic trienesilanes 7 also underwent analogou
