19043-29-9Relevant articles and documents
Aggregate formation and photoreactivity in phospholipid vesicles and Langmuir - Blodgett multilayers: Topologically controlled photodimerization of amphiphilic styrenes
Zhao, Xiao-Mei,Perlstein, Jerome,Whitten, David G.
, p. 10463 - 10467 (2007/10/02)
The amphiphilic styrene fatty acid 1 and its corresponding phosphatidylcholine derivative 2 have been found to exhibit aggregate formation and topologically controlled photodimerization in Langmuir - Blodgett (LB) assemblies and phospholipid vesicles, res
STEREOCONTROLLED PHOTOCHEMICAL CYCLOADDITION
Fleming, Steven A.,Ward, Susan C.
, p. 1013 - 1016 (2007/10/02)
Dimethyldicinnamyl- and diphenyldicinnamylsiloxane were synthesized from cinnamyl alcohol and dimethyl- and diphenyldichlorosilane, respectively.After photolysis, one cyclobutane product, the all trans isomer, was observed in nearly quantitative yield.Photolysis of cinnamyl alcohol under the same conditions results in very little cyclobutane formation. Key Words: stereoselective photocycloaddition, siloxane photochemistry, cyclobutane synthesis