190512-62-0

Upstream product

• 637-59-2 1-Bromo-3-phenylpropane 
• 111198-02-8 1-(phenoxymethyl)-1H-benzo[d][1,2,3]triazole 
• 28539-02-8 1-Hydroxymethyl-1H-benzotriazole 
• 54187-96-1 1-(chloromethyl)-1H-benzotriazole 
• 95-14-7 1,2,3-Benzotriazole 

Downstream Products

• 1370291-65-8 potassium 3-phenylpropanoyltrifluoroborate 
• 1027539-64-5 2-Benzotriazol-1-yl-1-(4-chloro-phenyl)-2-phenoxy-5-phenyl-pentan-1-one 
• 190512-65-3 2-Benzotriazol-1-yl-2-phenoxy-1,5-diphenyl-pentan-1-one 

Relevant academic research and scientific papers

Synthesis of acyltrifluoroborates

Acylboranes are among the most elusive boron-containing organic functional groups, a fact that has impeded development of new reactions employing them as substrates. A new synthesis of acyltrifluoroborates from benzotriazole (Bt)-based N,O-acetals has bee

Novel and Facile Syntheses of Alkenyl, Alkynyl, and Aryl 1,2-Diketones

Novel and facile routes to alkenyl, alkynyl, and aryl 1,2-diketones utilize treatment of benzotriazole derivatives 1, 7a,b, and 15a-d with butyllithium and subsequent reaction with esters or acid chlorides to yield the substituted intermediates 2a-d, 8a,b, and 16a-g, Reactions of the deprotonated 1 and 7 with α,β-unsaturated aldehydes followed by oxidation also produces similar intermediates 5 and 11a,b. Subsequent hydrolyses of the intermediates of type 2, 5, 8,11, and 16 afford diverse 1,2-diketones in good yields.