190602-70-1

Basic information

• Product Name: 1-Pyrrolidinecarboxylic acid, 2-[(phenylseleno)methyl]-, ethyl ester, (S)-
• CAS NO: 190602-70-1
• Molecular Formula: C14H19NO2Se
• Molecular Weight: 312.27
• Mol File: 190602-70-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-Pyrrolidinecarboxylic acid, 2-[(phenylseleno)methyl]-, ethyl ester, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Pyrrolidinecarboxylic acid, 2-[(phenylseleno)methyl]-, ethyl ester, (S)-(190602-70-1)
• EPA Substance Registry System: 1-Pyrrolidinecarboxylic acid, 2-[(phenylseleno)methyl]-, ethyl ester, (S)-(190602-70-1)

Safety Data

• Hazardous Substances Data: 190602-70-1(Hazardous Substances Data)

Upstream product

• 23356-96-9 (S)-1-Pyrrolidin-2-yl-methanol 
• 71098-88-9 N-phenylselanylphthalimide 
• 53310-79-5 ethyl (2S)-2-(hyroxymethyl)pyrrolidine-1-carboxylate 

Relevant articles and documents

Synthesis and substitution reactions of N-protected 2-(phenylselenonylmethyl)pyrrolidines

Alkyl phenyl selenides derived from the benzeneselenenyl chloride induced cyclization of N-protected pent-4-enylamines can be converted in good yield into the corresponding 2-hydroxymethyl- or 2-alkoxymethyl-substituted pyrrolidines by oxidation to the corresponding selenone, followed by reaction with water (or hydroxide) or with the corresponding alcohol. Details of the reactions and possible mechanisms for the substitution are discussed.