190730-97-3

Basic information

• Product Name: (E)-(η(5)-C5Me5)(CO)2FeP=CHN(Ph)N=C(NMe2)2
• CAS NO: 190730-97-3
• Molecular Weight: 496.372
• Mol File: 190730-97-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-(η(5)-C5Me5)(CO)2FeP=CHN(Ph)N=C(NMe2)2(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-(η(5)-C5Me5)(CO)2FeP=CHN(Ph)N=C(NMe2)2(190730-97-3)
• EPA Substance Registry System: (E)-(η(5)-C5Me5)(CO)2FeP=CHN(Ph)N=C(NMe2)2(190730-97-3)

Safety Data

• Hazardous Substances Data: 190730-97-3(Hazardous Substances Data)

Upstream product

• 508191-77-3 3-phenylsydnone 

Relevant articles and documents

Transition-metal-substituted acyl phosphanes and phosphaalkenes. 32. Transformation of an FeP=C unit of a phosphaalkene into a FeP=C-N-N=C moiety by chain extension through insertion of the 1,3-dipole (-N-N(Ar)-CH+) of sydnones

The metallophosphaalkene (η5-C5Me5)(CO)2FeP=C(NMe 2)2 (1) underwent reaction with sydnones 3-aryl-NNOC(O)CH (aryl = C6H5 (2a), 4-FC6H4 (2b), 4-ClC6H4 (2c), 4-BrC6H4 (2d)) to afford the novel ferriophosphaalkenes (η5-C5Me5)(CO) 2FeP=CHN(aryl)N=C(NMe2)2 (3a-d). Compound 3a forms the [2 + 2] phosphetanyl cycloadduct 4a with dimethyl fumarate. The molecular structure of 3a was determined by single-crystal X-ray diffraction.