190772-83-9Relevant academic research and scientific papers
Novel addition reactions of titanacycle phosphonates by tuning of Ti(O-i-Pr)4/2i-PrMgCl)
Quntar, Abed Al Aziz,Srebnik, Morris
, p. 58 - 59 (2007/10/03)
Di- or tri-substituted vinylphosphonates, 2-5, can be obtained in a highly regio- and stereoselective manner from 1-alkynylphosphonates, by manipulation of Ti(O-i-Pr)4/2i-PrMgCl.
Facile and stereoselective synthesis of vinylphosphonates
Cristau, Henri-Jean,Mbianda, Xavier Yangkou,Beziat, Yves,Gasc, Marie-Benedicte
, p. 301 - 311 (2007/10/03)
Stereoselective syntheses of mono-, di- and trisubstituted diethyl alk-1-enylphosphonates, starting from readily available alk-1-ynylphosphonates, have been developed, using catalytic hydrogenation or cuprate addition on the triple bond.
