19079-80-2

Basic information

• Product Name: Benzeneacetic acid, a-(1-Methylethyl)-, ethyl ester, (S)-
• Synonyms: Benzeneacetic acid, a-(1-Methylethyl)-, ethyl ester, (S)-
• CAS NO: 19079-80-2
• Molecular Formula: C₁₃H₁₈O₂
• Molecular Weight: 206.28082
• Mol File: 19079-80-2.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzeneacetic acid, a-(1-Methylethyl)-, ethyl ester, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzeneacetic acid, a-(1-Methylethyl)-, ethyl ester, (S)-(19079-80-2)
• EPA Substance Registry System: Benzeneacetic acid, a-(1-Methylethyl)-, ethyl ester, (S)-(19079-80-2)

Safety Data

• Hazardous Substances Data: 19079-80-2(Hazardous Substances Data)

Upstream product

• 582-62-7 3-methyl-1-phenylbutan-1-one 
• 122-51-0 orthoformic acid triethyl ester 
• 1117-96-0 Diazoethan 
• 13490-69-2 (S)-2-phenyl-3-methylbutyric acid 

Downstream Products

• 19643-71-1 (2S)-3-methyl-2-phenylbutan-1-ol 

Relevant articles and documents

Stereoselective Ketone Rearrangements with Hypervalent Iodine Reagents

The first stereoselective version of an iodine(III)-mediated rearrangement of arylketones in the presence of orthoesters is described. The reaction products, α-arylated esters, are very useful intermediates in the synthesis of bioactive compounds such as ibuprofen. With chiral lactic acid-based iodine(III) reagents product selectivities of up to 73 % ee have been achieved.