190968-26-4

Upstream product

• 60933-68-8 3,4,6-tri-O-benzyl-β-D-arabinofuranoside 
• 14233-53-5 3,4,6-tri-O-benzyl-D-arabinitol 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 197861-85-1 (3S,4R)-1,3,4-Tris-benzyloxy-5-(tert-butyl-diphenyl-silanyloxy)-pentan-2-one 
• 197861-90-8 4-[(1S,2R)-3-(tert-Butyl-diphenyl-silanyloxy)-1,2-dihydroxy-propyl]-4-hydroxy-dihydro-furan-2-one 
• 197861-87-3 (4S,5R)-4,5-Bis-benzyloxy-3-benzyloxymethyl-6-(tert-butyl-diphenyl-silanyloxy)-3-hydroxy-hexanoic acid ethyl ester 

Relevant academic research and scientific papers

Synthesis of 2',3',4'-trisphosphate-containing analogs of adenophostin A

Adenophostin A analog 4 was prepared via trimethylsilyl trifluoromethanesulfonate (TMSOTf)-assisted glycosylation of (S)-6-N-diphenylacetyl-9-(2-tert-butyldiphenylsilyloxy-1- hydroxyprop-3-yl)-adenine (11) with trichloroacetimidate donor 12 to give dimer

A short and efficient synthetic process to enantiomerically pure (+)-syributin 1

For the synthesis of (+)-syributin 1 produced by bacteria which expresses the avrD gene, a simple and practical synthetic route is described in a short number of steps and high overall yield featuring the elaboration of D-arabinofuranose derivative.