191-85-5Relevant academic research and scientific papers
Stereoselective tandem cascade furan cycloadditions
Criado, Alejandro,Vilas-Varela, Manuel,Cobas, Agustin,Perez, Dolores,Pena, Diego,Guitian, Enrique
, p. 12637 - 12649 (2013)
Oligofurans linked by a rigid tether undergo tandem cycloaddition reactions with high stereoselectivity. The reaction of bisfurans with dimethyl acetylenedicarboxylate (DMAD) involves tandem [4 + 2]/[4 + 2] cycloadditions in a pincer mode. The reaction of oligofurans with arynes involves stereoselective tandem [4 + 2]/[4 + 2] cycloaddition reactions in a domino mode. The corresponding aryne adducts have been transformed into extended perylene derivatives by deoxygenation and aromatization with HCl/EtOH.
Domino diels-alder cycloadditions of arynes: New approach to elusive perylene derivatives
Criado, Alejandro,Pena, Diego,Cobas, Agustin,Guitian, Enrique
, p. 9736 - 9740 (2010)
(Figure Presented) A game of dominos: Domino [4+2]/ [4+2] cycloadditions between 1,8-difurylnaphthalene and arynes provide the corresponding adducts in a highly diastereoselective manner. This new synthetic methodology enables the preparation of elusive perylene derivatives with a remarkable reduced HOMO-LUMO gap, a crucial feature for organic semiconductors.
Acid-promoted aromatization of perylene-based endoxides
Criado, Alejandro,Vilas-Varela, Manuel,Cobas, Agustín,Pérez, Dolores,Pe?a, Diego,Guitián, Enrique
, p. 1625 - 1632 (2016/11/13)
The aromatization of perylene-based endoxides by treatment with HCl and EtOH has been studied.
Organic compound having functional groups different in elimination reactivity at both terminals, organic thin film, organic device and method of producing the same
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, (2008/06/13)
Provided are a single monomolecular film uniform in film thickness and highly ordered in molecule alignment and its multilayer film, an organic compound allowing production of such films at high reproducibility, an organic device superior in electroconductive properties and a method of producing the same. An organic compound represented by Formula: Si(A1)(A2)(A3)-B—Si(A4)(A5)(A6) (A1 to A6 each represent a hydrogen atom, a halogen atom, an alkoxy group or an alkyl group and satisfy the relationship in elimination reactivity of: A1 to A3>A4 to A6; and B represents a bivalent organic group), an organic thin film using the compound, and an organic device having the thin film; A method of producing an organic thin film and organic device, comprising a step of forming a single monomolecular film by allowing the silyl group having A1 to A3 in the organic compound to react with the substrate surface; a step of removing unreacted organic compounds by using a non-aqueous solvent; and a step of forming an additional monomolecular film of the organic compound by using the unreacted silyl groups present on the film surface side of the monomolecular film obtained as the sites for adsorption reaction.
Organic electroluminescent device
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, (2008/06/13)
An electroluminescent device includes an anode, a cathode and at least one organic layer sandwiched between the anode and the cathode, the organic layer including a light-emitting layer which includes compound C1.
