19100-95-9

Basic information

• Product Name: 1-Hexanol, 6-(diphenylphosphinyl)-
• CAS NO: 19100-95-9
• Molecular Formula: C18H23O2P
• Molecular Weight: 302.353
• Mol File: 19100-95-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1-Hexanol, 6-(diphenylphosphinyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Hexanol, 6-(diphenylphosphinyl)-(19100-95-9)
• EPA Substance Registry System: 1-Hexanol, 6-(diphenylphosphinyl)-(19100-95-9)

Safety Data

• Hazardous Substances Data: 19100-95-9(Hazardous Substances Data)

Upstream product

• 40145-10-6 1-iodohexan-6-ol 
• 146964-28-5 Methyl 6-diphenylphosphinoylhexanoate 
• 73367-77-8 (5-carboxypentyl)diphenylphosphine oxide 
• 19100-91-5 6-hydroxyhexyl-triphenylphosphonium iodide 
• 821-41-0 5-Hexen-1-ol 
• 4559-70-0 Diphenylphosphine oxide 
• 2009-83-8 6-chloro-1-hexanol 

Downstream Products

• 146964-30-9 6-Diphenylphosphinoylnonane-1,7-diol 
• 146964-30-9 (6R,7S)-6-(Diphenyl-phosphinoyl)-nonane-1,7-diol 
• 146964-30-9 (6R,7R)-6-(Diphenyl-phosphinoyl)-nonane-1,7-diol 
• 89625-23-0 (3RS,4SR)-9-tert-Butyldimethylsilyloxy-4-diphenylphosphinoylnonan-3-ol 
• 89625-23-0 (3RS,4RS)-9-tert-Butyldimethylsilyloxy-4-diphenylphosphinoylnonan-3-ol 
• 31502-19-9 (Z)-6-nonenol 
• 31502-19-9 (E)-6-nonen-1-ol 
• 89625-22-9 1-(6-tert-Butyldimethylsilyloxyhexyl)diphenylphosphine Oxide 

Relevant articles and documents

A silver-initiated free-radical intermolecular hydrophosphinylation of unactivated alkenes

A scalable, operationally easy intermolecular hydrophosphinylation of various unactivated alkenes with H-P(O) compounds via an Ag(i)-initiated free radical process was developed. Mechanistic studies including electron-spin-resonance (ESR) and radical clock experiments suggest that atom transfer processes were involved in this system.

Air-induced anti-Markovnikov addition of secondary phosphine oxides and H-phosphinates to alkenes

(Chemical Equation Presented) Air (oxygen) induces the addition of secondary phosphine oxides and H-phosphinates to alkenes to selectively produce the corresponding anti-Markovnikov adducts in good to high yields. Mechanistic studies show that the addition probably proceeds via a radical chain mechanism.

SYNTHESIS OF SINGLE ISOMERS (E OR Z) OF UNSATURATED ALCOHOLS BY THE HORNER-WITTIG REACTION

Single isomers (E or Z) of homoallylic and higher alcohols can be synthesised from ω-hydroxyalkyldiphenylphosphine oxides and aldehydes, or from alkyldiphenylphosphine oxides and lactones