191099-37-3

Basic information

• Product Name: 5-Hexen-2-one, 3-(phenylseleno)-
• CAS NO: 191099-37-3
• Molecular Formula: C12H14OSe
• Molecular Weight: 253.203
• Mol File: 191099-37-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 5-Hexen-2-one, 3-(phenylseleno)-(CAS DataBase Reference)
• NIST Chemistry Reference: 5-Hexen-2-one, 3-(phenylseleno)-(191099-37-3)
• EPA Substance Registry System: 5-Hexen-2-one, 3-(phenylseleno)-(191099-37-3)

Safety Data

• Hazardous Substances Data: 191099-37-3(Hazardous Substances Data)

Upstream product

• 5707-04-0 Phenylselenyl chloride 
• 13893-90-8 benzoic acid isopropenyl ester 
• 106-95-6 allyl bromide 
• 34837-55-3 Phenylselenyl bromide 
• 108-22-5 Isopropenyl acetate 
• 71098-88-9 N-phenylselanylphthalimide 
• 109-49-9 5-Hexen-2-one 
• 61759-13-5 1-(phenylselanyl)propan-2-one 

Relevant articles and documents

Direct synthesis of regioselective α-allyl α-selanyl ketones and selanyl tetra-hydrofurans

An efficient approach for the synthesis of α-allyl α-selanyl ketone and selanyl tetrahydrofurans has been reported in this present work. The sodium methoxide (MeONa) mediated one pot three-component synthesis lead towards a good to an excellent yield of products with a wide substrate scope. The selenylated ketones can be important point towards important organic synthons.

Allylation and benzylation of enoltes derived from β-phenylselanyl silyl enol ethers

α-Phenylselanyl γ-unsaturated ketones were obtained through allylation of enolates generated by potassium t-butoxide cleavage of β-phenylselanyl silyl enol ethers derived from α-phenylselanyl ketones. With enoxysilanes prepared from α-phenylselanyl aldehydes, O-allylation and O-benzylation of the corresponding enolates were also observed.