191109-43-0

Basic information

• Product Name: 1,3-Dioxolan-2-one, 4-(4-methoxyphenyl)-, (4R)-
• CAS NO: 191109-43-0
• Molecular Formula: C10H10O4
• Molecular Weight: 194.187
• Mol File: 191109-43-0.mol

Chemical Properties

• CAS DataBase Reference: 1,3-Dioxolan-2-one, 4-(4-methoxyphenyl)-, (4R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Dioxolan-2-one, 4-(4-methoxyphenyl)-, (4R)-(191109-43-0)
• EPA Substance Registry System: 1,3-Dioxolan-2-one, 4-(4-methoxyphenyl)-, (4R)-(191109-43-0)

Safety Data

• Hazardous Substances Data: 191109-43-0(Hazardous Substances Data)

Upstream product

• 637-69-4 4-Methoxystyrene 
• 13603-63-9 (R)-1-(4-methoxyphenyl)ethane-1,2-diol 
• 616-38-6 carbonic acid dimethyl ester 

Downstream Products

• 191109-56-5 2-(Bis-{[(S)-2-hydroxy-1-(4-methoxy-phenyl)-ethylcarbamoyl]-methyl}-amino)-N-[(S)-2-hydroxy-1-(4-methoxy-phenyl)-ethyl]-acetamide 
• 191109-48-5 (S)-2-amino-2-(4-methoxyphenyl)-1-ethanol 
• 191109-46-3 (S)-2-azido-2-(p-methoxyphenyl)ethanol 

Relevant articles and documents

Asymmetric Allylic C-H Alkylation via Palladium(II)/ cis-ArSOX Catalysis

We report the development of Pd(II)/cis-aryl sulfoxide-oxazoline (cis-ArSOX) catalysts for asymmetric C-H alkylation of terminal olefins with a variety of synthetically versatile nucleophiles. The modular, tunable, and oxidatively stable ArSOX scaffold is key to the unprecedented broad scope and high enantioselectivity (37 examples, avg. > 90% ee). Pd(II)/cis-ArSOX is unique in its ability to effect high reactivity and catalyst-controlled diastereoselectivity on the alkylation of aliphatic olefins. We anticipate that this new chiral ligand class will find use in other transition metal catalyzed processes that operate under oxidative conditions.

Enantioselective allylic oxidation of cycloalkenes by using Cu(II)-tris(oxazoline) complex as a catalyst

Optically active copper(II)-tris(oxazoline) complex that was synthesized as a model compound of the active site of non-heme oxygenase, was found to catalyze allylic oxidation of cycloalkenes to give the corresponding 2-cycloalkenyl benzoates with moderate to excellent enantioselectivity (up to 93% ee) under die Kharash-Sosnovsky reaction conditions.