191112-26-2Relevant articles and documents
Highly enantioselective synthesis of chiral cyclic allylic amines via RH-catalyzed asymmetric hydrogenation
Zhou, Ming,Liu, Tang-Lin,Cao, Min,Xue, Zejian,Lv, Hui,Zhang, Xumu
supporting information, p. 3484 - 3487 (2014/07/21)
Highly regioselective and enantioselective asymmetric hydrogenation of cyclic dienamides catalyzed by an Rh-DuanPhos complex has been developed, which provides a readily accessible method for the synthesis of chiral cyclic allylic amines in excellent enantioselectivities (up to 99% ee). The products are valuable chiral building blocks and could be easily transformed to multisubstituted cyclohexane derivatives.
Pd-diimine: A highly selective catalyst system for the base-free oxidative heck reaction
Gottumukkala, Aditya L.,Teichert, Johannes F.,Heijnen, Dorus,Eisink, Niek,Van Dijk, Simon,Ferrer, Catalina,Van Den Hoogenband, Adri,Minnaard, Adriaan J.
supporting information; experimental part, p. 3498 - 3501 (2011/06/22)
Pd(OAc)2/3 is an efficient catalyst system for the base-free oxidative Heck reaction that outperforms the currently available catalysts for the more challenging substrates studied. The catalyst system is highly selective, and works at room temperature with dioxygen as the oxidant.
