191165-99-8Relevant academic research and scientific papers
Ruthenium-mediated dehydration of benzaldehyde oxime. X-ray crystal structure of the mixed-valence compound [RuBr(N≡CPh)5][RuBr4(N≡CPh)2] · PhCH2OH
Kukushkin, Yuri N.,Bavina, Marina V.,Zinchenko, Andrey V.,Belsky, Vitaly K.,Kukushkin, Vadim Yu.
, p. 2429 - 2433 (2008/10/09)
The reaction between RuBr3 · xH2O and benzaldehyde oxime in aqueous 6 M HBr results in facile metal-assisted dehydration of the oxime and concomitant partial reduction of ruthenium(III) to produce the mixed-valence ruthenium(III)-ruthenium(II) compound [RuBr(N≡CPh)5][RuBr4(N≡CPh)2]. This ionic complex has been structurally characterized as the monobenzyl alcohol solvate, [RuBr(N≡CPh)5][RuBr4(N≡CPh)2] · PhCH2OH.
