191172-12-0Relevant articles and documents
Syntheses and spectroscopic properties of palladium(II) complexes with bidentate phosphine and thiolate ligands. X-ray crystal structure of [Pd(SCH2Ph)2{Ph2P(CH2) 3PPh2}]
Su, Weiping,Cao, Rong,Hong, Maochun,Zhou, Zhongyong,Xie, Feng,Liu, Hanqin,Mak, Thomas C. W.
, p. 2531 - 2535 (1997)
By the reactions of Pd2+, thiolate (PhCH2S- or pdt) and dppe or dppp [pdt = SCH2CH2CH2S2-, dppe = 1,2-bis(diphenylphosphino)ethane, dppp = 1,3-bis(diphenylphosphino)propane] in MeOH, the following complexes, [Pd(SCH2Ph)2(dppe)] (1), [Pd(SCH2Ph)2(dppp)] (2) and [Pd(pdt)(dppp)] (3), were prepared. The crystal structure of 2 was analysed by single-crystal X-ray diffraction. The palladium atom is tetra-coordinated with a distorted square-planar geometry of two phosphorus and two sulfur atoms. Their IR, 31P and 1H NMR spectra are reported.