191172-12-0

Basic information

• Product Name: [Pd(SCH₂C₆H₅)2((C₆H₅)2PCH₂CH₂CH₂P(C₆H₅)2)]
• CAS NO: 191172-12-0
• Molecular Weight: 765.268
• Mol File: 191172-12-0.mol

Chemical Properties

• CAS DataBase Reference: [Pd(SCH₂C₆H₅)2((C₆H₅)2PCH₂CH₂CH₂P(C₆H₅)2)](CAS DataBase Reference)
• NIST Chemistry Reference: [Pd(SCH₂C₆H₅)2((C₆H₅)2PCH₂CH₂CH₂P(C₆H₅)2)](191172-12-0)
• EPA Substance Registry System: [Pd(SCH₂C₆H₅)2((C₆H₅)2PCH₂CH₂CH₂P(C₆H₅)2)](191172-12-0)

Safety Data

• Hazardous Substances Data: 191172-12-0(Hazardous Substances Data)

Upstream product

• 6737-42-4 1,3-bis-(diphenylphosphino)propane 
• 3492-64-6 sodium benzylmercaptide 

Relevant articles and documents

Syntheses and spectroscopic properties of palladium(II) complexes with bidentate phosphine and thiolate ligands. X-ray crystal structure of [Pd(SCH2Ph)2{Ph2P(CH2) 3PPh2}]

By the reactions of Pd2+, thiolate (PhCH2S- or pdt) and dppe or dppp [pdt = SCH2CH2CH2S2-, dppe = 1,2-bis(diphenylphosphino)ethane, dppp = 1,3-bis(diphenylphosphino)propane] in MeOH, the following complexes, [Pd(SCH2Ph)2(dppe)] (1), [Pd(SCH2Ph)2(dppp)] (2) and [Pd(pdt)(dppp)] (3), were prepared. The crystal structure of 2 was analysed by single-crystal X-ray diffraction. The palladium atom is tetra-coordinated with a distorted square-planar geometry of two phosphorus and two sulfur atoms. Their IR, 31P and 1H NMR spectra are reported.