191222-99-8Relevant academic research and scientific papers
Mild but efficient methods for stereoselective glycosylation with thioglycosides: Activation by [N-phenylselenophthalimide-Mg(ClO4)2] and [PhIO-Mg(ClO4)2]
Fukase, Koichi,Nakai, Yoshihiko,Kanoh, Takeshi,Kusumoto, Shoichi
, p. 84 - 86 (2007/10/03)
Combinations of N-phenylselenophthalimide (N-PSP) or iodosobenzene (PhIO) with Mg(ClO4)2 effectively promote glycosylation with thioglycosides under mild conditions. A 2,2,2-trichloroethoxycarbonyl group or trityl protecting group at
Trityl ethers in oligosaccharide synthesis: A novel strategy for the convergent assembly of oligosaccharides
Boons, Geert-Jan,Bowers, Simeon,Coe, Diane M.
, p. 3773 - 3776 (2007/10/03)
We have developed a novel glycosylation strategy in which a tritylated thioglycoside can act as a glycosyl donor and acceptor. In combination with previously reported chemoselective glycosylations, this feature enables highly convergent assembly of oligosaccharides.
