191232-73-2

Basic information

• Product Name: [μ-N-((anilino(5-methyl-2-thienyl)methyl)((2,3-η(1):η(2))-5-methyl-2-thienyl)methyl)-η(1):η(1)(N)-anilino]hexacarbonyldiiron
• CAS NO: 191232-73-2
• Molecular Weight: 682.34
• Mol File: 191232-73-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [μ-N-((anilino(5-methyl-2-thienyl)methyl)((2,3-η(1):η(2))-5-methyl-2-thienyl)methyl)-η(1):η(1)(N)-anilino]hexacarbonyldiiron(CAS DataBase Reference)
• NIST Chemistry Reference: [μ-N-((anilino(5-methyl-2-thienyl)methyl)((2,3-η(1):η(2))-5-methyl-2-thienyl)methyl)-η(1):η(1)(N)-anilino]hexacarbonyldiiron(191232-73-2)
• EPA Substance Registry System: [μ-N-((anilino(5-methyl-2-thienyl)methyl)((2,3-η(1):η(2))-5-methyl-2-thienyl)methyl)-η(1):η(1)(N)-anilino]hexacarbonyldiiron(191232-73-2)

Safety Data

• Hazardous Substances Data: 191232-73-2(Hazardous Substances Data)

Upstream product

• 15321-51-4 diiron nonacarbonyl 
• 80833-74-5 N-(5-methyl-2-thienylmethylidene)aniline 

Relevant articles and documents

Reaction of a thienyl schiff base with diiron nonacarbonyl: Characterization and structures of [μ-N-(((2,3-η1:η 2)-5-methyl-2-thienyl)methyl)-η1:η1 (N)-anilino]hexacarbonyldiiron and [μ-N-((anilino(2-thienyl)methyl) ((2,3-η1:η2)-2-thienyl)methyl)-η 1:η1(N)

When thienyl Schiff base 1 reacted with Fe2(CO)9 under very mild conditions in benzene three major products were obtained: (1) a cyclometalated (μ-η1:η2-thienyl; η1:η1(N))-hexacarbonyldiiron complex, 2, (2) a hexacarbonyldiiron complex with an organic ligand, which is composed of two thienyl moieties derived from the original thienyl imine and coupled together by a C-C bond, 3, and (3) a hydrogenation product of the original thienyl Schiff base. Molecular structures of compounds 2b and 3a have been determined by single-crystal X-ray diffraction.