191274-70-1

Basic information

• Product Name: [Ag(C₆H₅NCHNHC₆H₅)2(O₃SCF₃)]
• CAS NO: 191274-70-1
• Molecular Weight: 649.442
• Mol File: 191274-70-1.mol

Chemical Properties

• CAS DataBase Reference: [Ag(C₆H₅NCHNHC₆H₅)2(O₃SCF₃)](CAS DataBase Reference)
• NIST Chemistry Reference: [Ag(C₆H₅NCHNHC₆H₅)2(O₃SCF₃)](191274-70-1)
• EPA Substance Registry System: [Ag(C₆H₅NCHNHC₆H₅)2(O₃SCF₃)](191274-70-1)

Safety Data

• Hazardous Substances Data: 191274-70-1(Hazardous Substances Data)

Upstream product

• 2923-28-6 silver trifluoromethanesulfonate 
• 864131-95-3 N,N'-diphenylformamidine 

Relevant articles and documents

Bis(N,N′-diphenylformamidine)silver(I) triflate: A three-coordinate silver formamidine compound stabilized by intramolecular hydrogen bonds

A formally three-coordinate silver(I) complex, Ag(HDPhF)2(OSO2CF3) (1), has been prepared from the reaction of AgSO3CF3 with HDPhF (HDPhF = N,N′-diphenylformamidine) in toluene and characterized through spectroscopic methods and single-crystal X-ray diffraction studies. The silver atom is bound through one nitrogen atom each to two neutral formamidine ligands and weakly coordinated to the triflate anion through an oxygen atom. The AgN2O group is practically planar with an N - Ag - N angle of 142.3(2)° and O - Ag - N angles of 122.4(2) and 92.0(1)°. Hydrogen bonding possibly related to the mechanism of formamidine cleavage seen in other complexes occurs between oxygen atoms of the triflate anion and amine hydrogen atoms in 1.